The brother who wanted the throne
In Thor (2011), Loki sabotages his brother's coronation by letting Frost Giants into Asgard's vault and then eggs Thor on to strike back at Jotunheim. Odin banishes Thor to Earth. In the middle of all this, Loki discovers the truth about himself: he's a Frost Giant, Laufey's son, taken in as a baby by Odin after a war.
With Odin sunk in the Odinsleep, Loki takes the throne, sends the Destroyer after Thor on Earth, lures Laufey into a trap and kills him, and tries to wipe out Jotunheim using the Bifrost. Thor comes back, destroys the bridge and holds his brother over the abyss. When Odin says "no," Loki lets go and falls into the void.