Qui-Gon's master
Tales of the Jedi shows Dooku decades before he became a villain. He's an elegant, demanding Jedi Master with a young Qui-Gon Jinn as his apprentice. On a mission to rescue a senator's son, he sees the Republic protect the powerful and ignore the suffering of ordinary people, and he doesn't forget it.
Later, he and Mace Windu investigate the death of Master Katri on Raxus Secundus, against the Council's wishes. When Mace gets a seat on the Jedi Council and Dooku doesn't, his distrust of the Order and the Senate only grows.